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Assessment of the adsorption kinetics, equilibrium and thermodynamics for the potential removal of Ni²⁺ from aqueous solution using waste eggshell

    Sukru Aslan Affiliation
    ; Ayben Polat Affiliation
    ; Ugur Savas Topcu Affiliation

Abstract

In this study, Ni2+ sorption onto the waste eggshell was investigated under different operational conditions. Results indicated that the eggshell could be successfully used to remove Ni2+ ions from the water. Quick sorption process reached to equilibrium in about 2 hours with maximum sorption at pH 7.0. Based on the experimental data, Langmuir isotherm model with the qm value of 1.845 mg Ni2+/g eggshell was observed. The pseudo-second-order model provided the best correlation coefficient in comparison with other models. The calculated qe values derived from the pseudo-second-order for sorption of Ni2+ ions were very close to the experimental (qexp) values. Such thermodynamic parameters as ΔG°, ΔH°, and ΔS° were determined in order to predict the nature of adsorption. Results indicated that the adsorption of Ni2+ onto the eggshell was endothermically supported by the increasing adsorption of Ni2+ ions with temperature.

Keyword : adsorption isotherms, eggshell, nickel, thermodynamics

How to Cite
Aslan, S., Polat, A., & Topcu, U. S. (2015). Assessment of the adsorption kinetics, equilibrium and thermodynamics for the potential removal of Ni²⁺ from aqueous solution using waste eggshell. Journal of Environmental Engineering and Landscape Management, 23(3), 221-229. https://doi.org/10.3846/16486897.2015.1005015
Published in Issue
Sep 29, 2015
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This work is licensed under a Creative Commons Attribution 4.0 International License.